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four-CL-PVP CRYSTAL is classed as being a substituted cathinone. The substituted cathinones are multitudinous and diversified. Their defining capabilities certainly are a phenethylamine spine by using a ketone at the beta placement and an alkyl substituent within the alpha placement to the carbon adjacent on the nitrogen.
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As chlorine is extremely electrophilic the profile of electrostatic charge through the molecule will probably be altered, permanently or negative. Sterically it may even change binding, but once more substitutions during the para posture are actually properly tolerated in other cathinones like four MMC.